While the primary function of a storage system is to provide power when sunlight is not available, hence increasing the fraction of time the photovoltaic system provides electricity, the addition of batteries has numerous other advantages which mean that the batteries can be used for multiple purposes. For small systems consisting of one or two photovoltaic modules, batteries can act as a load-matching system. Alternately, in photovoltaic systems which contain a load with a large initial current draw (such as experienced by an inductive load, typically represented by a motor), the batteries can be used to provide initial start-up current. In grid-connected systems, battery storage can be used for peak shifting, in which the power generated by the sun is stored for several hours in order to better match when the peak load occurs.
In various useful units, the universal gas constant can be written
R = 8.3144 x 107 erg mol-1 K-1
= 8.3144 J mol-1 K-1
= 8.2057 x 10-2 l atm mol-1 K-1
= 1.9872 cal mol-1 K-1
= 62.363 l torr cal mol-1 K-1
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The alkaline battery consists of a redox reaction in which the anode is Zn (which also usually the casing) with an electrolyte consisting of a paste of NaOH or KOH. The half reactions are:

In this battery, if one mole of zinc is present, and two moles of MnO2, then the Zn is the limiting component for the reaction.